According to the manual: [
php.net]
Since PHP 5.3.0, PHP includes support for .htaccess-style INI files on a per-directory basis. These files are processed only by the CGI/FastCGI SAPI. This functionality obsoletes the PECL htscanner extension. If you are using Apache, use .htaccess files for the same effect. Unfortunately WAMP does not use CGI or Fast/CGI modes it runs php as a included module.
This si probably the reason it is ignoring your php.ini in the website folder(s).