That shouldn't be an issue either. Just edit the mysql configuration file so that "datadir" points to the data on the new drive.
*you'll wanna shutdown MySql and then copy the the ..wamp/mysql/data directory to where-ever. Then edit the my.ini file and change the datadir path to point to the new location... Then of course start mySql back up... This is of course only if you have databases that you want to move... You'd also have to edit the httpd.conf file as mentioned above.
Post Edited (01-23-07 17:11)