Hi,
> it won't connect,
What you call "won't connect" should be clearly defined and detailed.
There are built-in tools that allow, among other things, to test port 80 and change the port used by Apache, have you used them?
What is the result of the port 80 test?
> localhost/***/WordPress
Web applications in general and Wordpress in particular must be installed and used in a VirtualHost.
See
The need for Virtual Host---------------------------------------------------------------
Documentation Apache -
Documentation PHP -
Documentation MySQL -
Wampserver install files & addons