they are already services (that is why the menu says "start all services"
right click on your "my computer" icon (either on your desktop on in Explorer)
go to "mange"
click on services
find wampapache and wampmysql
double click on one at a time
drop down in middle (most likely says "manual"
click the arrow and set to automatic
do that for each one.
they should autostart when you start up windows.